| 5-30 | HF Gurney | Nottinghamshire v Derbyshire | 2019 | tt7994 |
| 4-11 | T Lungley | Derbyshire v West Indians | 2007 | tt652 |
| 4-11 | AJ Ireland | Leicestershire v Derbyshire | 2013 | tt3750 |
| 4-13 | T Lungley | Derbyshire v Nottinghamshire | 2003 | tt19 |
| 4-14 | AG Botha | Derbyshire v West Indians | 2007 | tt652 |
| 4-14 | E Chigumbura | Northamptonshire v Derbyshire | 2010 | tt1860 |
| 4-15 | G Keedy | Lancashire v Derbyshire | 2008 | tt919 |
| 4-17 | Imran Tahir | Derbyshire v Worcestershire | 2017 | tt6435 |
| 4-18 | MA Ashraf | Yorkshire v Derbyshire | 2012 | tt2978 |
| 4-20 | HF Gurney | Nottinghamshire v Derbyshire | 2016 | tt5773 |
| 4-21 | CD Whelan | Worcestershire v Derbyshire | 2011 | tt2241 |
| 4-21 | BW Sanderson | Yorkshire v Derbyshire | 2011 | tt2340 |
| 4-21 | TD Groenewald | Derbyshire v Lancashire | 2013 | tt3668 |
| 4-22 | P Coughlin | Durham v Derbyshire | 2017 | tt6426 |
| 4-24 | GD Clough | Nottinghamshire v Derbyshire | 2007 | tt642 |
| 4-26 | LH Ferguson | Derbyshire v Nottinghamshire | 2018 | tt7038 |
| 4-27 | BJ Hodge | Lancashire v Derbyshire | 2005 | tt220 |
| 4-32 | N Killeen | Durham v Derbyshire | 2003 | tt32 |
| 4-35 | JDS Neesham | Derbyshire v Lancashire | 2016 | tt5822 |
| 4-36 | MJJ Critchley | Derbyshire v Worcestershire | 2019 | tt8053 |
| 4-40 | CJ Russell | Worcestershire v Derbyshire | 2014 | tt4376 |
| 4-40 | JT Ball | Nottinghamshire v Derbyshire | 2022 | tt10893 |