| 8-66 | SRG Francis | Somerset v Derbyshire | 2004 | a15870 |
| 7-35 | DE Malcolm | Derbyshire v Northamptonshire | 1997 | a10603 |
| 6-14 | OH Mortensen | Derbyshire v Ireland | 1989 | a6108 |
| 6-26 | SR Lampitt | Worcestershire v Derbyshire | 1994 | a8642 |
| 6-28 | SR Barwick | Glamorgan v Derbyshire | 1993 | a8038 |
| 6-31 | N Killeen | Durham v Derbyshire | 2000 | a12939 |
| 6-31 | G Welch | Derbyshire v Middlesex | 2002 | a14575 |
| 6-34 | RD Jackman | Surrey v Derbyshire | 1972 | a657 |
| 6-51 | JE Home | Worcestershire v Derbyshire | 2024 | a31025 |
| 6-65 | AJ Tye | Australia A v Derbyshire | 2019 | a27431 |
| 5-11 | A Ward | Derbyshire v Sussex | 1970 | a338 |
| 5-17 | NA Foster | Essex v Derbyshire | 1986 | a4869 |
| 5-17 | PJ Bakker | Hampshire v Derbyshire | 1989 | a6171 |
| 5-18 | DG Cork | Derbyshire v Berkshire | 1992 | a7613 |
| 5-18 | G Welch | Derbyshire v Gloucestershire | 2002 | a14390 |
| 5-21 | IR Payne | Surrey v Derbyshire | 1982 | a3411 |
| 5-22 | G Welch | Derbyshire v Glamorgan | 2001 | a13391 |
| 5-24 | CJ Tunnicliffe | Derbyshire v Yorkshire | 1981 | a2924 |
| 5-24 | CJ Tunnicliffe | Derbyshire v Northamptonshire | 1981 | a3102 |
| 5-24 | JAR Blain | Northamptonshire v Derbyshire | 1997 | a10680 |
| 5-25 | TD Topley | Essex v Derbyshire | 1988 | a5631 |
| 5-27 | DE Malcolm | Derbyshire v Middlesex | 1988 | a5679 |
| 5-29 | JG Thomas | Northamptonshire v Derbyshire | 1991 | a6978 |
| 5-32 | ALF de Mel | Sri Lanka v New Zealand | 1983 | a3702 |
| 5-32 | WKM Benjamin | Leicestershire v Derbyshire | 1992 | a7643 |
| 5-32 | KJ Dean | Derbyshire v Gloucestershire | 1996 | a9987 |
| 5-37 | S Oldham | Derbyshire v Lancashire | 1982 | a3373 |
| 5-37 | PR Brown | Derbyshire v Lancashire | 2024 | a31011 |
| 5-39 | KA Parsons | Somerset v Derbyshire | 2004 | a15899 |
| 5-40 | PADLR Sandakan | Sri Lanka A v Derbyshire | 2016 | a24818 |
| 5-41 | AA Donald | Warwickshire v Derbyshire | 1995 | a9360 |
| 5-45 | KJ Dean | Derbyshire v Leicestershire | 2005 | a16650 |
| 5-48 | R Rampaul | Derbyshire v Yorkshire | 2018 | a26456 |
| 5-49 | AP Palladino | Derbyshire v Lancashire | 2014 | a23463 |
| 5-56 | ID Austin | Lancashire v Derbyshire | 1991 | a7036 |
| 5-56 | LJ Fletcher | Nottinghamshire v Derbyshire | 2019 | a27295 |
| 5-57 | GC Small | Warwickshire v Derbyshire | 1984 | a4117 |
| 5-60 | AG Botha | Derbyshire v West Indies A | 2006 | a17546 |