| 6-21 | HO von Rauenstein | Free State v North West | 2009/10 | a20033 |
| 6-22 | Z Pongolo | Gauteng v Free State | 2018/19 | a26883 |
| 6-24 | Imran Tahir | South Africa v Zimbabwe | 2018/19 | a26735 |
| 6-26 | JE Bastow | KwaZulu-Natal v Free State | 2000/01 | a13270 |
| 6-33 | CA Dry | Free State v South Western Districts | 2013/14 | a23054 |
| 6-41 | BM Mathebula | Gauteng v Free State | 2006/07 | a17658 |
| 6-58 | LT Ngidi | South Africa v Australia | 2019/20 | a28018 |
| 5-21 | JF Venter | Orange Free State v Transvaal | 1993/94 | a8371 |
| 5-25 | SC van Schalkwyk | Free State v Boland | 2019/20 | a27752 |
| 5-26 | M Ntini | Warriors v Eagles | 2009/10 | a20252 |
| 5-26 | GA Vries | Free State v Northerns | 2010/11 | a21034 |
| 5-27 | PL Harris | Titans v Eagles | 2008/09 | a19441 |
| 5-30 | RJ Peterson | Eastern Province v Free State | 2001/02 | a13838 |
| 5-30 | RK Terblanche | Free State v KwaZulu-Natal Inland | 2020/21 | a28251 |
| 5-33 | GW Coetzee | Free State v Northerns | 2018/19 | a26815 |
| 5-37 | D Stanley | Easterns v Free State | 2015/16 | a24468 |
| 5-39 | CJD de Villiers | Free State v North West | 2007/08 | a18765 |
| 5-42 | L Klusener | South Africa v India | 1996/97 | a10323 |
| 5-50 | LM Zuma | KwaZulu-Natal Inland v Free State | 2019/20 | a27814 |
| 5-54 | RD McMillan | South Western Districts v Free State | 2011/12 | a21954 |
| 5-59 | M de Lange | Free State v Namibia | 2016/17 | a25003 |